Preheat your oven to 400°F for roasting the garlic.
Place the garlic cloves (with skins on) on a small piece of foil, drizzle with a tiny bit of olive oil, and wrap the foil loosely.
Roast the garlic in the preheated oven for 25-30 minutes until soft and caramelized.
While the garlic roasts, pat the pork chop dry with paper towels.
Combine chopped fresh rosemary and thyme in a small dish. Add a pinch of salt and black pepper.
Rub the herb mixture evenly over both sides of the pork chop.
Heat a non-stick skillet over medium-high heat and add the olive oil.
Sear the pork chop for about 3-4 minutes on each side until a golden-brown crust forms.
Once seared, lower the heat slightly and continue to cook until the internal temperature reaches your preferred doneness, about 6-8 minutes total depending on thickness.
Remove the pork chop from the skillet and let it rest for a couple of minutes.
Squeeze the roasted garlic out of its skins and serve alongside the pork chop.