Pat the shrimp dry with paper towels and toss in a bowl with arrowroot powder, sea salt, and black pepper until lightly coated.
In a small jar or bowl, whisk together the raw honey, coconut aminos, minced garlic, and grated fresh ginger to create the glaze.
Heat the toasted sesame oil in a large skillet or wok over medium-high heat.
Add the shrimp to the skillet and sear for 2 minutes per side until they turn pink and develop a slight golden crust, then remove from the pan and set aside.
In the same skillet, add the broccoli florets and sliced red bell pepper, sautéing for 3 to 4 minutes until they are tender-crisp and bright.
Return the cooked shrimp to the skillet and pour the honey-garlic glaze over the shrimp and vegetables.
Toss everything together for 1 to 2 minutes until the sauce thickens and becomes glossy, coating every piece evenly.
Divide the warm cooked brown rice into bowls and top with the shrimp stir-fry, finishing with a garnish of sesame seeds and sliced green onions.