Pat the chicken breast dry with paper towels, dice into one-inch cubes, and toss in a bowl with arrowroot powder, sea salt, and black pepper until evenly coated.
In a small bowl, whisk together the honey, coconut aminos, minced garlic, and sesame oil until the mixture is smooth and the honey is fully incorporated.
Heat the olive oil in a large non-stick skillet over medium-high heat; add the chicken cubes in a single layer and sear for 3-4 minutes per side until golden and crispy.
While the chicken is searing, place the broccoli florets in a steamer basket over boiling water and steam for 4-5 minutes until they are tender-crisp and vibrant green.
Reduce the skillet heat to medium, pour the honey-garlic sauce over the chicken, and toss for 1-2 minutes until the sauce bubbles and thickens into a glossy glaze.
Assemble the bowls by layering the cooked jasmine rice at the base, topping with the glazed chicken and steamed broccoli, and garnishing with sesame seeds.