Preheat your oven to 400°F (200°C) and place a wire rack over a large parchment-lined baking sheet.
Pat the chicken wings completely dry with paper towels to ensure the skin becomes crispy during roasting.
In a large bowl, lightly toss the wings with avocado oil, sea salt, black pepper, and garlic powder until evenly coated.
Arrange the wings in a single layer on the wire rack and bake for 35 to 40 minutes, flipping halfway through, until golden brown.
While the wings are roasting, whisk together the honey, coconut aminos, rice vinegar, and toasted sesame oil in a small saucepan.
Place the saucepan over medium heat and simmer for 2 to 3 minutes until the sauce reduces slightly into a thin, sticky glaze.
Steam the broccoli florets in a steamer basket for about 5 minutes until they are tender-crisp and bright green.
Transfer the hot wings to a clean bowl, pour the honey glaze over them, and toss well to coat each wing thoroughly.
Garnish the wings with sesame seeds and sliced green onions, then serve immediately alongside the steamed broccoli.