Rinse the white rice under cold water until clear, then combine with 0.5 cups of water in a small pot. Bring to a boil, reduce heat to low, cover, and simmer for 15 minutes.
While rice cooks, season the chicken breast on both sides with sea salt and black pepper.
Heat olive oil in a non-stick skillet over medium-high heat. Add the chicken and sear for 5-6 minutes per side until golden and cooked through.
While chicken is searing, steam the broccoli florets in a steamer basket for 4-5 minutes until tender-crisp.
In a small bowl, whisk together the honey, tamari, and minced garlic.
Lower the skillet heat to medium. Pour the honey-garlic mixture over the chicken, turning the breast to coat thoroughly as the sauce bubbles and thickens into a glaze.
Fluff the rice with a fork and plate it alongside the steamed broccoli.
Slice the chicken, place it over the rice, and drizzle any remaining pan sauce over the top.
Garnish with sesame seeds before serving.